login
N掺杂TiO2负载金属催化剂研究
2025/11/07·StepFun can make mistakes, check important info.
请推荐几篇涉及N掺杂TiO2负载金属催化剂的论文

Requirement clarification

我需要为用户推荐涉及N掺杂TiO2负载金属催化剂的论文。这是一个专业学术领域的需求，需要通过搜索获取最新、最相关的研究论文信息。

首先，我将通过网络搜索获取相关论文信息。

搜索

Search

N-doped TiO2 metal catalyst research papers
文件
文件
[PDF] 可见光活性掺杂 T iO 改性研究进展
文件
文件
[PDF] ORIGINAL RESEARCH ARTICLE
文件
文件
[PDF] Nitrogen and Carbon Nitride-Doped TiO for Multiple Catalysis and Its Antimicrobial Activity
文件
文件
[PDF] (19)中华人民共和国国家知识产权局
sciencedirect.com
sciencedirect.com
by K Park · 2023 · Cited by 22 — A single atom Ru catalyst supported on a N-doped TiO2 was investigated for the conversion of CO2 to formate by hydrogenation.
pubs.rsc.org
by J Zhang · 2010 · Cited by 771 — This paper presents a critical review of novel achievements in the modification of N–TiO 2 photocatalytic systems aimed at enhancing TiO 2 applications.
手机知网
手机知网
<em>TiO2</em> 氮<em>掺杂 金属</em>修饰 光<em>催化</em> 丙烯 苯酚 期刊全文库 学位<em>论文</em>库 会议<em>论文</em>库 年鉴全文库 学术百科 工具书 个人查重 我的账户 基础科学|工程科技I辑|工程科技II辑|医药卫生科技|信息科技|农业科技|哲学与人文科学|社会科学I辑|社会科学II辑|经济管理 问答 个人查重&gt;&gt;个人AIGC检测&gt;&gt;
m.fanwen118.com
m.fanwen118.com
然而，由于锐钛矿型 TiO 2 的禁带宽度为 3.2 ev，只对紫外光有吸收能力，限制了 TiO 2 在可见光下的光催化能力。随着人们对太阳能资源有效利用的迫切需求，为了拓宽 TiO 2 的光吸收宽度，人们通常通过采取金属（Fe [11] 、Ni、Cr等）/非金属（N [12] 、C、B、S等）的掺杂方式，加强 TiO 2 的光催化降解能力，将光吸收宽度扩大至可将光区域。最近，有报道关于N [13] 、S [14] 、C [15] 、F和N [16] 共掺杂到具有（001）面的锐钛矿 TiO 2 催化剂中，均表现出良好的可见光光催化性能。虽然，关于过渡金属 Fe 掺杂到 TiO 2 催化剂中的可见光催化性能研究已经报道很多 [11,17] ，但关于 Fe 元素掺杂的具有（001）面的锐钛矿 TiO 2 催化剂的紫外/可见光催化性能还未有人研究。而且，多级 TiO 2 纳米片通常具有很高的结晶度，通过利用温和的手段在后处理时进行掺杂不太可能，另外，在反应过程中通过添加掺杂剂的前体会对晶体的成核与生长产生很大影响以至于得不到我们预想的结构和形貌 [12] 。
https://static-favicon.basemind.com/01JVC9V86CMD19H75R4RPCNPH3
https://static-favicon.basemind.com/01JV20D5BJF7J32QM97C7P9PCC
https://s2.zimgs.cn/ims?kt=url&at=smstruct&key=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&sign=yx:YBIFeW5bj8FSwZm2L2FEiQeEvpI=&tv=400_400
View all 19 sources

基于搜索结果，我可以看到N掺杂TiO2负载金属催化剂是一个活跃的研究领域，涉及光催化、可见光响应和多种应用场景。为了更好地理解用户需求，我需要分析核心需求和可能的研究方向。

用户需要的是N掺杂TiO2负载金属催化剂相关论文推荐，这类催化剂通常结合了氮掺杂改性TiO2的可见光响应能力和金属催化活性。从搜索结果看，这类材料主要应用于光催化降解有机污染物、CO2转化、氢能生产等领域。

搜索结果显示了多篇相关论文，包括Pd/TiO2、Ru/TiO2、Fe掺杂TiO2等不同金属体系，以及不同的制备方法和应用场景。我可以根据这些信息推荐具体论文，但需要确认用户对哪些方面更感兴趣。

  1. 您对哪类金属负载在N掺杂TiO2上更感兴趣(如贵金属Pt/Pd/Au、过渡金属Fe/Cu/Co等)？
  2. 您更关注催化剂的哪些应用领域(如光催化降解污染物、CO2还原、产氢等)？
  3. 您是否需要包含催化剂制备方法或机理研究的论文？
跳过

好的，这是为您制定的行动计划。

Research plan
  1. 分析和归类已提供的搜索结果，识别出论文的核心主题，例如具体的金属种类（如Ru、Ag、Fe）、催化应用（如光催化降解、CO2还原）以及文章类型（如综述、研究论文）。
  2. 在已有的搜索结果中，优先筛选出综述性文章，这些文章通常发表在RSC、Springer、万方数据等学术平台上，能够为该领域提供一个全面的概述。
  3. 根据催化剂的创新性、应用的独特性以及发表期刊的影响力，从ScienceDirect、ACS Publications、中国知网等来源中挑选出具有代表性的原创研究论文。
  4. 针对每一篇被选中的论文，从其摘要或正文中提取关键信息，包括论文标题、作者、发表年份、期刊名称以及核心研究内容和结论的简要概括。
  5. 将筛选出的论文按照“综述文章”和“具体应用研究”等逻辑进行分类，以便于结构化呈现。
  6. 整合所有信息，形成一份包含论文分类、关键信息摘要的推荐列表，作为最终的成果输出。
开始研究

Deep Research

首先，让我搜索关于N掺杂TiO2负载金属催化剂的相关论文。

搜索

Search

N-doped TiO2 metal catalyst research papers
文件
文件
[PDF] 可见光活性掺杂 T iO 改性研究进展
文件
文件
[PDF] ORIGINAL RESEARCH ARTICLE
文件
文件
[PDF] Nitrogen and Carbon Nitride-Doped TiO for Multiple Catalysis and Its Antimicrobial Activity
文件
文件
[PDF] (19)中华人民共和国国家知识产权局
sciencedirect.com
sciencedirect.com
by K Park · 2023 · Cited by 22 — A single atom Ru catalyst supported on a N-doped TiO2 was investigated for the conversion of CO2 to formate by hydrogenation.
pubs.rsc.org
by J Zhang · 2010 · Cited by 771 — This paper presents a critical review of novel achievements in the modification of N–TiO 2 photocatalytic systems aimed at enhancing TiO 2 applications.
手机知网
手机知网
<em>TiO2</em> 氮<em>掺杂 金属</em>修饰 光<em>催化</em> 丙烯 苯酚 期刊全文库 学位<em>论文</em>库 会议<em>论文</em>库 年鉴全文库 学术百科 工具书 个人查重 我的账户 基础科学|工程科技I辑|工程科技II辑|医药卫生科技|信息科技|农业科技|哲学与人文科学|社会科学I辑|社会科学II辑|经济管理 问答 个人查重&gt;&gt;个人AIGC检测&gt;&gt;
X技术
X技术
本发明属于催化剂领域，尤其涉及金属掺杂纳米TiO2光催化剂及其制备方法。 背景技术： TiO2光催化技术近年来在空气治理和污水处理方面的研究越来越广泛，对于环境的可持续发展具有深远意义。但是由于
https://static-favicon.basemind.com/01JVAVW432RKQWESFQSQHMR87A
https://static-favicon.basemind.com/01JVC9V86CMD19H75R4RPCNPH3
https://static-favicon.basemind.com/01JV1VHWSCDXZZ04AZTRHWDBGN
View all 18 sources

我将为您推荐几篇涉及N掺杂TiO2负载金属催化剂的高质量论文。让我先搜索更多相关信息，特别是关注最新的研究进展。

搜索

Search

N-doped TiO2 metal catalyst recent papers 2023 2024
researchgate.net
researchgate.net
Interstitial N-Doped TiO2 for Photocatalytic Methylene Blue Degradation under Visible Light Irradiation. MDPI. Catalysts. October 2024; 14(10): ...
nature.com
nature.com
by M Narimani · 2025 · Cited by 6 — This study is focused on the synthesis and evaluation of TiO2 and N-doped Ti3O5 for the photocatalytic degradation of phenol as a noxious substance commonly ...
百度学术
百度学术
展开 关键词：TiO_2 N掺杂 光催化 机理 TiO_2 N-doped photocatalysis mechanismDOI：CNKI:CDMD:2.2009.242978来源学校重庆工商大学文献可以 啦~欢迎点我试用！
好发表
摘要： 半导体光催化剂因可以直接利用太阳光进行光催化且不产生二次污染,成为一种应用于环境污染治理领域较为理想的材料。其中TiO2光催化剂具有较高的光稳定性、良好的化学性质、无毒、较低的成本、高的光催化效率等特点,目前受到广泛的研究与关注。然而,TiO2快速复合的电子-空穴及较大的禁带宽度等自身缺陷,导致其量子产率不高,TiO2中的电子只能在紫外光下被激发,这些因素使得它的光催化性能受到了制约。因此,近年来通过研究不同的金属元素掺杂TiO2基光催化剂及研究不同特殊微纳结构来克服TiO2自身缺陷以改善其光催化性能并取得较大的进展。研究发现,通过将不同金属(如Ag、Fe、Cu、Ce等)以一元、二元、多元的形式掺入TiO2中,可改善TiO2的自身缺陷,并在催化剂表面产生不同作用,使其光响应范围增大,光催化性能显著提升。此外,研究者们还发现,特殊微纳结构的存在可以加快金属掺杂TiO2基光催化材料的电子转移,从而提高TiO2光生电子-空穴的分离效率,增加了其量子产率。金属掺杂后,TiO2对有机物的降解率及其产氢能力、光能转化率都得到了显著的提高,使其不仅在紫外光下具有优异的性能,而且在可见光下也能进行良好的光催化。掺杂后TiO2的抗菌效果与防雾性能也得到了显著的提升。本文一方面综述了不同金属掺杂体系(一元、二元复合以及多元复合掺杂)对TiO2结构及其光催化性能的改变,总结不同制备工艺对TiO2结构与性能的影响规律,并分析光催化性能的增强机制。另一方面概述了金属掺杂TiO2基复合材料的一些特殊微纳结构包括石墨烯包覆结构、核-壳结构以及其他结构的制备工艺,并讨论了不同微纳结构与金属掺杂在增强TiO2光催化性能上所起的作用。最后简单综述了不同金属掺杂TiO2纳米复合材料的不同应用,展望了未来研究方向及�
zhangqiaokeyan.com
zhangqiaokeyan.com
mechanism of doped was analyzed.The photocatalytic activities were highest when the proportion of N-doped was n(N): n (TiO2) =4:1 and Ag-doped was n(Ag of co-doped TiO2 (molar ratio n (TiO2)∶ n (N)∶ n (Ag) = 1∶ 4∶ 0.02) was higher than single-doped.The degradation rates was∶ pure TiO2, 40％; N-doped, 75 ％; Ag-doped, 70％ and co-doped, 84％ respectively.It proved that the mechanisms of metal-doped and non-metal-doped affected together in co-doped photocatalyst
mdpi.com
mdpi.com
by Z Zhang · 2024 · Cited by 8 — Our work offers a facile strategy for the preparation of N-TiO 2 with Vo via the annealing treatment with urea.
link.springer.com
link.springer.com
by X Li · 2024 · Cited by 9 — Herein, we engineered ruthenium (Ru) FTS catalysts supported on N-doped carbon overlayers on TiO2 nanoparticles. By regulating the carbonization ...
sciencedirect.com
sciencedirect.com
by DH Lim · 2024 · Cited by 19 — This study offers deep insights into the practical utility of N–TiO 2 for the photocatalytic mineralization of aldehyde VOCs.
https://static-favicon.basemind.com/01JV1VHWSCDXZZ04AZTRHWDBGN
View all 10 sources

我需要更具体地了解关于N掺杂TiO2负载金属催化剂的最新研究，特别是关注一些具体的金属催化剂类型。让我搜索更多相关信息。

搜索

Search

Ru Pd Pt loaded on N-doped TiO2 catalyst recent papers
文件
文件
[PDF] An Overview of Palladium-Catalyzed Nalkylation Reactions
sciencedirect.com
sciencedirect.com
by Y Dong · 2025 · Cited by 6 — The Pt/N–TiO2–ST catalyst exhibits high catalytic performance with hydrogenation of FAL to FOL. Abstract. Highly efficient synthesis of valuable ...
pubs.acs.org
pubs.acs.org
In the selective hydrogenation of nitroarenes, TiO2- supported catalysts have been developed in previous reports.32−34 It has been found that ...
papers.ssrn.com
The Pt/TiO2@CN-x. 10 catalyst was further loaded with Pt NPs on the support and finally synthesized. 11 successfully. In contrast, TiO2@CN-525 and Pt/TiO2@C ...
百度学术
百度学术
并且根据DFT计算,分析了SiC表面氧的作用,SiC表面部分氧化后,仍保持对Pd的较高结合能,同时大幅增强了催化剂对中间体的吸附,降低了ORR关键电化学步骤的吉布斯自由能,从而提高了ORR性能。(4)通过在氨气气氛下高温煅烧TiO_2(B),制备了N掺杂TiO_2(N-TiO_2),并采用直接热解法将Pd NPs(平均粒径为2.8 nm)负载到N-TiO_2上,制得Pd/N-TiO_2催化剂。研究结果表明,随着煅烧温度的升高(700,800,900℃),N-TiO_2中Ti-O逐渐减少(55.1%减少至43.1%),而Ti-N-O、Ti-N逐渐增多(25.9%增加至31.9%,19.0%增加至25.0%),说明N部分取代了TiO_2中的O,TiO_2表面生成了具有氧还原活性的TiO_xN_y和具有导电性质的TiN,而且负载Pd NPs后,发生了由载体到Pd的电子转移,促进了Pd基催化剂氧还原活性的提高。同时,由于Pd与载体之间的强相互作用,使催化剂也具有较强的稳定性。
www.x-mol.com
www.x-mol.com
通过氨基功能化钛金属有机骨架NH 2 -MIL -125(Ti)在空气中直接热解制备氮掺杂TiO 2 (N-TiO 2 )，并将高度分散的AuPd纳米颗粒锚定在N-TiO 2 上。合成的催化剂表现出优异的甲酸脱氢活性。60℃时,Au 2 Pd 8 /N-TiO 2 催化的脱氢反应总周转频率值为7725 h -1 ,是无氮催化剂(Au 2 Pd 8 /TiO 2 )的2.9倍。相同条件下。Au 2 Pd的优异性能 8 /N-TiO 2 催化剂归因于锐钛矿型TiO 2 含量高、N-TiO 2 载体与金属纳米粒子之间的协同效应、Au与Pd之间的合金化效应以及金属粒子的小尺寸。N的存在可以增强AuPd与载体之间的相互作用，有效阻止AuPd在载体表面的聚集，提高催化剂的催化活性和可重复使用性。 TiO 2晶相（锐钛矿和金红石）和N掺杂对Au 2 Pd 8 /N-TiO 2 性能的影响 通过理论计算分析了-催化的甲酸分解。结果表明，锐钛矿基和N-TiO 2 基催化剂可以降低甲酸脱氢的势垒。该工作将实验与理论计算相结合，为甲酸脱氢催化剂的改性提供了一种新的方法。
zhangqiaokeyan.com
zhangqiaokeyan.com
考察了Pt促进的N掺杂TiO2(Pt/N-TiO2)催化剂对光催化降解有机污染物性能的影响及其作用本质.采用X射线衍射、透射电镜、X射线光电子能谱、紫外-可见漫反射光谱、光电化学和荧光光谱等手段对催化剂进行了表征,并考察了样品在可见光下光催化降解甲基橙(MO)的反应性能.结果表明,Pt的存在并未明显改变N-TiO2的晶相和介孔结构,却增强了催化剂对可见光吸收,但这种背景吸收不利于光激发中心(N-TiO2)对可见光的吸收,从而影响Pt/N-TiO2光催化活性;高度分散在N-TiO2表面的Pt,显著地改变了催化剂表面电子结构,从而提高了N-TiO2的光催化性能.%The influence of Pt as a promoter on the photocatalytic performance of nitrogen-doped TiO2 was described. The sample was characterized by X-ray diffraction. transmission electron microscopy, X-ray photoelectron spectroscopy, UV-Vis diffuse reflectance spectroscopy,photoelectrochemistry, and photoluminescence. The degradation of methyl orange in aqueous solution under visible light irradiation was used to evaluate the photocatalytic activity of the sample. The modification of N-TiO2 with Pt did not change the crystal structure and the mesoporous structure of TiO2. The loading of Pt enhanced the material absorption in visible light region, which is assigned to background absorption that has detrimental effect on photocatalytic activity. However, the highly dispersed Pt on the surface of N-TiO2 remarkably altered the surface structure (surface state) of N-TiO2. contributing largely to the enhanced photocatalytic activity of nitrogen-doped TiO2.
researchgate.net
researchgate.net
The highest hydrogen production rate (2460 μmol h−1 g−1) was obtained when bimetallic 0.05 wt% PdO-0.10 wt% Pt/N–TiO2 was used. After three ...
https://static-favicon.basemind.com/01JVBN8XHWBH6M4GHH6XVVK7VW
https://static-favicon.basemind.com/01JV2AF0F7S39CXN9B7TYMM3KC
https://static-favicon.basemind.com/01J7E9YA8AD76D5AP3RKNDWDP3
View all 11 sources

我需要查看一些具体的论文内容，以便更好地了解N掺杂TiO2负载金属催化剂的最新研究进展。让我查看其中一篇关键论文的详细内容。

网页解析

网页解析

https://www.sciencedirect.com/science/article/pii/S0926337323005167

已掌握的信息

  1. 核心研究领域：研究的核心是“N掺杂TiO2”作为载体，负载“金属”纳米颗粒构成复合催化剂。这种改性策略旨在克服纯TiO2仅能利用紫外光的局限性，拓展其在可见光下的催化活性。
  2. 关键改性机理：N元素的掺杂能够有效减小TiO2的带隙，增强其对可见光的吸收能力。负载的金属（尤其是贵金属如Pt, Pd, Ru, Au）不仅可以作为活性位点，还能促进光生电子-空穴对的分离，抑制其复合，从而显著提高催化效率。N掺杂还能诱导强金属-载体相互作用（SMSI），进一步提升催化剂的活性和稳定性。
  3. 主要催化应用：该类催化剂被广泛应用于多个领域，包括：
    • 环境治理：光催化降解水体和空气中的有机污染物（如亚甲基蓝、苯酚、醛类挥发性有机物）。
    • 能源转换：光催化产氢（如甲酸脱氢）、CO2还原制备燃料。
    • 精细化工合成：选择性加氢反应（如硝基芳烃加氢）。
  4. 代表性催化体系：已有的研究覆盖了多种金属，特别是贵金属。例如，Pt/N-TiO2在选择性加氢和污染物降解中表现优异；AuPd/N-TiO2在甲酸脱氢产氢方面活性很高；Ru/N-TiO2则在CO2加氢等领域受到关注。

下一步行动计划

  1. 系统化信息提取与整合：
    • 目标：针对已筛选出的几篇代表性论文（覆盖Pt、Pd、Ru、AuPd等不同金属体系），深入分析其核心内容。由于直接访问部分论文全文受阻，将优先在Google Scholar, ResearchGate, Baidu Xueshu等学术平台寻找开放获取版本或详细摘要。
    • 提取要点：重点提取每篇论文的催化剂制备方法、关键结构表征结果（如金属粒径、N掺杂形式）、催化反应类型、性能数据（如转化率、选择性、周转频率）以及提出的催化机理。
  2. 构建研究报告框架并填充内容：
    • 目标：搭建一个逻辑清晰的报告结构，并用上一步提取的信息填充各个模块。
    • 报告框架：
      • 引言：概述TiO2光催化剂的优势与瓶颈，引出N掺杂与金属负载协同改性的重要性。
      • 核心催化体系剖析：分小节详细介绍不同金属（Pt, Pd, Ru等）负载N-TiO2催化剂的典型研究案例。每个案例将围绕“制备-结构-性能-机理”四个方面展开。
      • 共性机理探讨：综合不同研究，总结N掺杂与金属负载之间协同作用的普遍规律，如图解说明其如何增强光吸收、促进电荷分离和活化反应物。
      • 总结与展望：归纳该领域的研究现状，并对未来发展方向（如新型金属负载、机理的深入探究、实际应用挑战等）进行展望。
  3. 数据可视化与图表制作：
    • 目标：为了使报告“图文并茂”，将关键信息转化为可视化图表。
    • 可视化方案：
      • 创建对比表格：制作一个总结性的表格，横向对比不同论文中的催化剂体系、目标反应、关键性能指标和发表期刊/年份，使成果一目了然。
      • 绘制机理示意图：根据论文中的描述，绘制一幅通用的机理示意图，形象地展示在可见光照射下，电子如何从N掺杂的TiO2跃迁，并被金属纳米颗粒捕获，从而驱动催化反应的全过程。
搜索

Search

Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation
华南理工大学
华南理工大学
... Experimental and theoretical understanding of nitrogen doping-induced strong metal-support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation.
semanticscholar.org
semanticscholar.org
Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation.
谷歌
谷歌
Experimental and Theoretical Understanding of Nitrogen Doping-Induced Strong Metal-Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation.
pubs.acs.org
pubs.acs.org
by P Chen · 2017 · Cited by 177 — By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
researchgate.net
researchgate.net
By doping the TiO2 support with nitrogen, strong metal-support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
中国地质图书馆
ACS电子期刊 命中： 43 条，耗时：0.0317184 秒 在所有数据库中总计命中： 1,718 条 1. Experime n tal a n d Theoretical U n dersta n di n g of Nitroge n -Dopi n g-I n duced Stro n g Metal–Support I n teractio n s i n Pd/TiO2 Catalysts for Nitrobe n ze n e Hydroge n atio n 作者： Peir o n g Che n ; Abhishek Kheta n ; Fe n gkai Ya n g ; Vadim Migu n ov ; Philipp Weide ; Sascha P. Stürmer ; Pe n ghu Guo ; Kevi n Kähler ; Wei Xia ; Joachim Mayer ; Hei n z Pitsch ; Ulrich Simo n ; Marti n Muhler 刊名：ACS Catalysis 出版年：2017 2. I n sights i n to I n terfacial Cha n ges a n d Photoelectrochemical Stability of I n xGa1‿i>xN (0001) Photoa n ode Surfaces i n Liquid E n viro n me n ts 作者： Lore n zo Caccamo ; Giulio Cocco ; Gemma Martí n ; Hao Zhou ; Sö n ke Fu n dli n g ; Alaaeldi n Gad ; Mati n Sadat Mohajera n i ; Mahmoud Abdelfatah ; So n ia Estradé ; Fra n cesca Peir ó ; Wa n ja Dzio n y ; Heiko Bremers ; A n dreas Ha n gleiter ; Leo n hard Mayrhofer ; Gerhard Lilie n kamp ; Michael Moseler ; Wi n fried Daum ; A n dreas Waag 刊名：ACS Applied Materials & I n terfaces 出版年：2016 3. 3D Visualizatio n of the Iro n Oxidatio n State i n FeO/Fe3O4 Core–Shell Na n ocubes from Electro n E n ergy Loss Tomography 作者： Pau Torruella ; Raúl Are n al ; Fra n cisco de la Peña ; Zi n eb Saghi ; Lluís Yedra ; Alberto Eljarrat ; Lluís López-Co n esa ; Marta Estrader ; Alberto López-Ortega ; Germá n Salazar-Alvarez ;
中国地质图书馆
在“ ACS电子期刊 ”中， 命中： 103 条，耗时：小于0.01 秒 在所有数据库中总计命中： 1,467 条 1. Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation 作者： Peirong Chen ; Abhishek Khetan ; Fengkai Yang ; Vadim Migunov ; Philipp Weide ; Sascha P. Stürmer ; Penghu Guo ; Kevin Kähler ; Wei Xia ; Joachim Mayer ; Hei nz Pitsch ; Ulrich Simon ; Martin Muhler 刊名：ACS Catalysis 出版年：2017 2. Molecular Design for Tailoring a Single-Source Precursor for Bismuth Ferrite 作者： Georg Bendt ; Rafael Schiwon ; Soma Salamon ; Joachim Landers ; Ulrich Hagemann ; Christian Limberg ; Hei ko Wende ; Stephan Schulz 刊名：Inorganic Chemistry 出版年：2016 3. Bay-Extended, Distorted Perylene Esters Showing Visible Luminescence after Ultraviolet Excitation: Photophysical and Electrochemical Analysis 作者： Joachim Vollbrecht ; Christian Wiebeler ; Adam Neuba ; Harald Bock ; Stefan Schumacher ; Hei nz Kitzerow 刊名：Journal of Physical Chemistry C 出版年：2016 4. Chemically Diverse Group I p21-Activated Kinase (PAK) Inhibitors Impart Acute Cardiovascular Toxicity with a Narrow Therapeutic Window 作者： Joachim Rudolph ; Lesley J. Murray ; Chudi O. Ndubaku ; Thomas O’Brien ; Elizabeth Blackwood ; Weiru Wang ; Ignacio Aliagas ; Lewis Gazzard ; James J. Crawford ; Joy Drobnick ; Wendy Lee ; Xianrui Zhao ; Klaus P. Hoeflich ; David A. Favor ; Ping Dong ;
pubs.acs.org
pubs.acs.org
by P Chen · 2017 · Cited by 177 — By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
https://static-favicon.basemind.com/01JVBN8XHWBH6M4GHH6XVVK7VW
View all 9 sources

我需要查看这篇论文的更多详细信息，让我尝试获取更多内容。

搜索

Search

Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation full text
researchgate.net
researchgate.net
By doping the TiO2 support with nitrogen, strong metal-support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
pubs.acs.org
pubs.acs.org
by P Chen · 2017 · Cited by 177 — By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
sciencedirect.com
sciencedirect.com
by Y Shao · 2025 · Cited by 4 — Experimental and theoretical understanding of nitrogen-doping-induced strong metal–support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation ...
中国地质图书馆
ACS电子期刊 命中： 43 条，耗时：0.0317184 秒 在所有数据库中总计命中： 1,718 条 1. Experime n tal a n d Theoretical U n dersta n di n g of Nitroge n -Dopi n g-I n duced Stro n g Metal–Support I n teractio n s i n Pd/TiO2 Catalysts for Nitrobe n ze n e Hydroge n atio n 作者： Peir o n g Che n ; Abhishek Kheta n ; Fe n gkai Ya n g ; Vadim Migu n ov ; Philipp Weide ; Sascha P. Stürmer ; Pe n ghu Guo ; Kevi n Kähler ; Wei Xia ; Joachim Mayer ; Hei n z Pitsch ; Ulrich Simo n ; Marti n Muhler 刊名：ACS Catalysis 出版年：2017 2. I n sights i n to I n terfacial Cha n ges a n d Photoelectrochemical Stability of I n xGa1‿i>xN (0001) Photoa n ode Surfaces i n Liquid E n viro n me n ts 作者： Lore n zo Caccamo ; Giulio Cocco ; Gemma Martí n ; Hao Zhou ; Sö n ke Fu n dli n g ; Alaaeldi n Gad ; Mati n Sadat Mohajera n i ; Mahmoud Abdelfatah ; So n ia Estradé ; Fra n cesca Peir ó ; Wa n ja Dzio n y ; Heiko Bremers ; A n dreas Ha n gleiter ; Leo n hard Mayrhofer ; Gerhard Lilie n kamp ; Michael Moseler ; Wi n fried Daum ; A n dreas Waag 刊名：ACS Applied Materials & I n terfaces 出版年：2016 3. 3D Visualizatio n of the Iro n Oxidatio n State i n FeO/Fe3O4 Core–Shell Na n ocubes from Electro n E n ergy Loss Tomography 作者： Pau Torruella ; Raúl Are n al ; Fra n cisco de la Peña ; Zi n eb Saghi ; Lluís Yedra ; Alberto Eljarrat ; Lluís López-Co n esa ; Marta Estrader ; Alberto López-Ortega ; Germá n Salazar-Alvarez ;
中国地质图书馆
在“ ACS电子期刊 ”中， 命中： 103 条，耗时：小于0.01 秒 在所有数据库中总计命中： 1,467 条 1. Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation 作者： Peirong Chen ; Abhishek Khetan ; Fengkai Yang ; Vadim Migunov ; Philipp Weide ; Sascha P. Stürmer ; Penghu Guo ; Kevin Kähler ; Wei Xia ; Joachim Mayer ; Hei nz Pitsch ; Ulrich Simon ; Martin Muhler 刊名：ACS Catalysis 出版年：2017 2. Molecular Design for Tailoring a Single-Source Precursor for Bismuth Ferrite 作者： Georg Bendt ; Rafael Schiwon ; Soma Salamon ; Joachim Landers ; Ulrich Hagemann ; Christian Limberg ; Hei ko Wende ; Stephan Schulz 刊名：Inorganic Chemistry 出版年：2016 3. Bay-Extended, Distorted Perylene Esters Showing Visible Luminescence after Ultraviolet Excitation: Photophysical and Electrochemical Analysis 作者： Joachim Vollbrecht ; Christian Wiebeler ; Adam Neuba ; Harald Bock ; Stefan Schumacher ; Hei nz Kitzerow 刊名：Journal of Physical Chemistry C 出版年：2016 4. Chemically Diverse Group I p21-Activated Kinase (PAK) Inhibitors Impart Acute Cardiovascular Toxicity with a Narrow Therapeutic Window 作者： Joachim Rudolph ; Lesley J. Murray ; Chudi O. Ndubaku ; Thomas O’Brien ; Elizabeth Blackwood ; Weiru Wang ; Ignacio Aliagas ; Lewis Gazzard ; James J. Crawford ; Joy Drobnick ; Wendy Lee ; Xianrui Zhao ; Klaus P. Hoeflich ; David A. Favor ; Ping Dong ;
National Institutes of Health (.gov)
National Institutes of Health (.gov)
by H Zou · 2021 · Cited by 75 — ... theoretical understanding of nitrogen-doping-induced strong metal–support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation.
researchgate.net
researchgate.net
This review seeks to provide a consolidated view of the current understanding of SMSI in TiO2‐supported metal catalysts. It highlights the ...

我需要查看一篇关于Pt负载N-TiO2催化剂的论文，以获取更多具体信息。

搜索

Search

Highly Effective N-TiO2 Supported Pt Catalyst for Selective Hydrogenation full text
pubs.acs.org
pubs.acs.org
Herein, an efficient N-TiO2 supported Pt catalyst was synthesized, which exhibits better catalytic performance than an undoped Pt/TiO2 catalyst in the ...
researchgate.net
researchgate.net
Tuning of catalytic sites in Pt/TiO2 catalysts for the chemoselective hydrogenation of 3-nitrostyrene. Article. Full-text available. Oct 2019.
acs.figshare.com
acs.figshare.com
Herein, an efficient N-TiO2 supported Pt catalyst was synthesized, which exhibits better catalytic performance than an undoped Pt/TiO2 catalyst ...
X-MOL
X-MOL
图4. Pt/Ti O 2 -TCO催化性能评价: (a-d) Pt/TiO 2 -TCO (T: 200-600 °C)催化剂对4-NS的选择性加氢，(e) 0.05 wt% Pt/TiO 2 -SAC催化剂上4-NS的加氢(反应条件：4-NS, 0.5 mmol; 催化剂, 90 mg; EtOH, 5 mL; P H2 , 0.5 MPa; T, 60°C)，(f) 硝基苯和苯乙烯混合物加氢，(g) 4-VA在60°C下6.0 h内加氢反应趋势, (h, i) Pt/TiO 2 -600CO在半转化和全转化条件下4-NS选择性加氢的循环稳定性(反应条件：4-NS或4-VA, 0.5 mmol; 催化剂, 10 mg; EtOH, 5 mL; P H2 , 0.5 MPa; T, 60°C, t, 50或120 min)。
掌桥科研
掌桥科研
The hydrogenation of crotonaldehyde in the presence of supported platinum nanoparticles was used to determine how the interaction between the metal particles and their support can control catalytic performance.Using gas-phase catalytic reaction studies and in situ sum-frequency generation vibrational spectroscopy (SFG) to study Pt/TiO2 and Pt/SiO2 catalysts, a unique reaction pathway was identified for Pt/TiO2, which selectively produces alcohol products.
AmazonAWS
Highly effective N-TiO2 supported Pt catalyst for selective hydrogenation of nitroarenes under mild conditions. Jing Lia, XinweiDu a, Yujing ...
sciencedirect.com
sciencedirect.com
by Y Dong · 2025 · Cited by 6 — The Pt/N–TiO2–ST catalyst exhibits high catalytic performance with hydrogenation of FAL to FOL. Abstract. Highly efficient synthesis of valuable ...
mdpi.com
mdpi.com
In this study, we synthesized a series of catalysts comprising TiO2-supported Pt nanoparticles with varying particle sizes, which were systematically evaluated ...
https://static-favicon.basemind.com/01JV3GETNJ8XHZD6B9GS95G5WQ
View all 10 sources

让我搜索一篇关于Ru负载在N-TiO2上的催化剂的论文，以获取更全面的信息。

搜索

Search

Ru catalyst supported on N-doped TiO2 CO2 conversion
文件
文件
[PDF] Light-assisted carbon dioxide reduction in an automated photoreactor system coupled to carbonylation chemistry
文件
文件
[PDF] (19)中华人民共和国国家知识产权局
文件
文件
[PDF] Advances in the studies of the supported ruthenium catalysts for $\mathbf { C O } _ { 2 }$ methanation
researchgate.net
researchgate.net
A single atom Ru catalyst supported on a N-doped TiO2 was investigated for the conversion of CO2 to formate by hydrogenation. N-dopant sites ...
sciencedirect.com
sciencedirect.com
by KR Lee · 2025 · Cited by 2 — We developed a rational strategy to enhance the catalytic performance of Ru catalysts supported on mesoporous N-doped TiO 2 for CO 2 hydrogenation.
ccspublishing.org.cn
In summary, the Ru-doped TiO2 photocatalysts with tunable oxygen vacancies have been successfully synthesized by using ascorbic acid as a reducing agent. In a ...
掌桥科研
掌桥科研
机译： 一锅超临界合成制备的N掺杂TiO2基光催化剂光催化还原CO2 获取原文 获取原文并翻译 | 示例 摘要 The objective of this work was to analyze the effect of carbon support on the activity and selectivity of N-doped TiO2 nanoparticles. Thus, N-doped TiO2 and two types of composites, N-doped TiO2/CNT and N-doped TiO2/rGO, were prepared by a new environmentally friendly one-pot method. CNT and rGO were used as supports, triethylamine and urea as N doping agents, and titanium (IV) tetraisopropoxide and ethanol as Ti precursor and hydrolysis agent, respectively. The as-prepared photocatalysts exhibited enhanced photocatalytic performance compared to TiO2 P25 commercial catalyst during the photoreduction of CO2 with water vapor. It was imputed to the synergistic effect of N doping (reduction of semiconductor band gap energy) and carbon support (enlarging e(-)-h(+) recombination time). The activity and selectivity of catalysts varied depending on the investigated material. Thus, whereas N-doped TiO2 nanoparticles led to a gaseous mixture, where CH4 formed the majority compared to CO, N-doped TiO2/CNT and N-doped TiO2/rGO composites almost exclusively generated CO. Regarding the activity of the catalysts, the highest production rates of CO (8 mu mol/gTiO(2)/h) and CH4 (4 mu mol/gTiO(2)/h) were achieved with composite N-1/TiO2/rGO and N-1/TiO2 nanoparticles, respectively, where superscript represents the ratio mg N/g TiO2. These rates are four times and almost forty times higher than the CO and CH4 production rates observed wi
百度
百度
In this work, we reported Ru nanoparticles (NPs) (<5 nm) supported on titanium dioxide (TiO2) using the facile and fast molten-salt method and employed Moreover, the catalytic applications of Ru/TiO2 were explored for the reductive amination of nitrobenzene and furfural with excellent conversion (>99%) catalyst compared to as-synthesized Cu/TiO2, and Ni/TiO2.
https://static-favicon.basemind.com/01JVBKBHYZ4FSRVA54KNXG1MPA
https://s2.zimgs.cn/ims?kt=url&at=smstruct&key=aHR0cHM6Ly9jZG4uc20uY24vdGVtcC8yMDIzMTEwODEwMjgwMS1zY2VsdXFpYWlicGpqb3hyZWdsb2s1Y3B0dWdteXMzbS5qcGc=&sign=yx:rWswce9emvVrFpo6R_aTBrpVXNY=&tv=400_400
https://static-favicon.basemind.com/01JVCF6NZGC4VDBKHS7B22GZY3
View all 18 sources

已掌握的信息

  1. 核心机理与优势: 已经明确N掺杂TiO2负载金属催化剂的核心优势在于协同效应。N掺杂通过在TiO2能带结构中引入N 2p轨道，有效降低了其禁带宽度，使其具备可见光响应能力。负载的贵金属（如Pt, Pd, Ru）纳米颗粒作为电子捕获中心，能高效促进光生电子-空穴对的分离，并作为催化活性位点。此外，N掺杂还能诱导强金属-载体相互作用（SMSI），这对于稳定金属纳米颗粒、调控其电子结构从而提升催化活性和选择性至关重要。
  2. 代表性催化体系与应用: 已通过初步调研锁定了几个关键的研究方向和代表性催化剂体系：
    • Pd/N-TiO2: 在硝基芳烃选择性加氢反应中表现出色，其高活性和选择性被归因于N掺杂诱导的强金属-载体相互作用。
    • Pt/N-TiO2: 同样在选择性加氢领域（如硝基芳烃加氢）展现出优于未掺杂载体的催化性能。
    • Ru/N-TiO2: 在CO2资源化利用（如CO2加氢制甲酸盐或甲烷化）方面显示出巨大潜力，N掺杂位点对稳定Ru活性物种起着关键作用。
    • AuPd/N-TiO2: 在甲酸脱氢产氢等能源催化领域具有高活性。
  3. 信息获取的挑战: 发现直接访问特定论文全文（尤其是通过出版商网站如ACS, ScienceDirect）存在障碍，但通过ResearchGate、Google Scholar等学术平台可以有效获取到论文的摘要、图表乃至全文（如果开放获取）。

下一步行动计划

  1. 关键论文的深度信息提取与整合: 针对已锁定的Pd、Pt、Ru负载于N-TiO2的几篇代表性论文，将绕过直接访问原文的障碍，通过在ResearchGate、Google Scholar等平台进行靶向搜索，力求获取其开放获取版本或详尽的摘要与核心图表。重点从这些材料中提炼并整合以下四类核心信息：
    • 制备方法: 催化剂的具体合成路线，包括N源、掺杂条件、金属负载方法等。
    • 关键性能: 催化活性和选择性的核心数据，例如转化率、产率、周转频率（TOF）等。
    • 构效关系: 论文中揭示的催化剂结构（如金属粒径、N掺杂形式）与催化性能之间的关联。
    • 催化机理: 作者提出的关于N掺杂与金属负载如何协同作用以提升催化性能的机理模型。
  2. 构建结构化研究报告并填充内容: 基于上一步提取的深度信息，搭建一份逻辑清晰、内容翔实的研究报告。报告将包含以下核心模块：
    • 引言: 概述TiO2光催化的基本原理与局限，引出N掺杂与金属负载协同改性的研究背景与重要意义。
    • 核心体系剖析: 分别设立章节，对Pd/N-TiO2、Pt/N-TiO2、Ru/N-TiO2等关键体系进行案例分析，围绕“制备-性能-构效关系-机理”展开详细论述。
    • 协同机理的可视化与总结: 综合不同研究案例，绘制一幅通用的协同催化机理示意图，直观展示可见光激发、电荷分离、电子向金属传递以及表面催化反应的全过程。同时，制作一个对比表格，横向比较不同金属催化剂体系在特定应用中的性能优劣、机理异同及制备特点。
    • 总结与展望: 对当前研究现状进行归纳总结，并对该领域未来的发展方向，如新金属体系的探索、机理研究的深化、面向工业应用的挑战等，进行科学展望。
网页解析

网页解析

https://www.researchgate.net/publication/370952479_Structural_effects_of_nitrogen-doped_titanium_oxide_supports_on_stabilization_of_ruthenium_active_species_in_carbon_dioxide_hydrogenation_to_formate

让我继续搜索关于Pt负载在N-TiO2上的催化剂的详细信息。

网页解析

网页解析

https://www.researchgate.net/publication/396674958_Highly_Effective_N-TiO_2_Supported_Pt_Catalyst_for_Selective_Hydrogenation_of_Nitroarenes_under_Mild_Conditions

我需要获取更多关于Pd/N-TiO2催化剂的信息，让我查看之前搜索到的论文。

网页解析

网页解析

https://www.researchgate.net/publication/311807430_Experimental_and_Theoretical_Understanding_of_Nitrogen_Doping-Induced_Strong_Metal-Support_Interactions_in_PdTiO2_Catalysts_for_Nitrobenzene_Hydrogenation

现在我已经收集了足够的信息，让我整理一份关于N掺杂TiO2负载金属催化剂的综合报告。

可视化工具

可视化工具

已掌握的信息

  1. 核心协同机理: 已明确N掺杂与金属负载在TiO2催化剂中存在显著的协同效应。N掺杂通过改变TiO2的电子能带结构，赋予其可见光吸收能力；同时，N掺杂位点能诱导强金属-载体相互作用（SMSI），这对于稳定负载的金属纳米颗粒、调控其电子态和提高分散度至关重要。
  2. 代表性催化体系与应用: 已成功调研并分析了多种贵金属负载的N-TiO2催化剂体系。例如，Pd/N-TiO2和Pt/N-TiO2在硝基芳烃选择性加氢反应中表现出高活性与高选择性；Ru/N-TiO2在CO2加氢制甲酸盐等碳中和相关领域展现出优异的稳定性，其中取代型氮（Ns）的作用尤为关键；AuPd/N-TiO2则在甲酸脱氢产氢方面活性突出。
  3. 关键论文信息: 已针对上述几种代表性催化剂，锁定了发表在高水平期刊（如ACS Catalysis, Applied Catalysis B）上的关键研究论文，并成功提取了其核心研究内容、方法、性能数据及结论，为构建综合性报告奠定了坚实基础。

下一步行动计划

  1. 撰写并整合研究报告内容: 将依据已掌握的信息，撰写一份结构完整的综合性研究报告。报告将首先从引言部分概述该领域的研究背景与意义，然后分章节详细阐述Pd、Pt、Ru等不同金属负载N-TiO2催化剂的典型研究案例，最后对协同催化机理进行归纳总结，并对未来发展方向进行展望。
  2. 创建机理示意图以实现图文并茂: 为了更直观地解释N掺杂与金属负载的协同作用机理，将构思并生成一幅通用的机理示意图。该图将清晰展示在可见光照射下，光生电子如何从N掺杂TiO2载体跃迁并被金属纳米颗粒捕获，进而驱动催化反应的全过程，从而增强报告的可读性与专业性。
  3. 生成最终综合性报告: 将撰写好的报告文本、先前已生成的核心论文对比表格以及新创建的催化机理示意图进行有机结合，形成一份内容全面、逻辑清晰、图文并茂的最终研究成果，以完整解答用户的调研任务。
可视化工具

可视化工具

我需要重新设计一个更简单的图表来展示N掺杂TiO2负载金属催化剂的协同作用机理。

执行代码

执行代码

python

现在我已经收集了足够的信息，并整理了关键数据表格和机理总结，让我为您提供一份关于N掺杂TiO2负载金属催化剂的综合研究报告。

N掺杂TiO2负载金属催化剂研究论文推荐

引言

N掺杂TiO2负载金属催化剂因其优异的光催化性能和广泛的应用前景，近年来受到研究者的广泛关注。N掺杂能够有效减小TiO2的带隙，增强其对可见光的吸收能力，而金属负载则能进一步提高催化活性和选择性。基于对现有文献的系统调研，以下推荐几篇在该领域具有重要影响力的研究论文，涵盖不同金属催化剂体系及其应用。

推荐论文

1. Pd/N-TiO2催化剂研究

论文标题： "Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation"

作者： Peirong Chen等

发表期刊： ACS Catalysis (2017)

研究亮点： 该论文系统研究了氮掺杂对Pd/TiO2催化剂中强金属-载体相互作用(SMSI)的影响。研究发现氮掺杂产生了结构促进效应，有利于Pd物种在TiO2上的高分散，形成亚2nm的Pd纳米颗粒researchgate.net。通过X射线光电子能谱(XPS)和CO-DRIFTS等表征手段，研究揭示了Pd与氮掺杂TiO2之间形成了强耦合的Pd-N物种，这对硝基苯加氢反应的催化性能有显著促进作用pubs.acs.org。

该研究的重要性在于：首次系统阐明了氮掺杂如何通过调控SMSI来提高Pd/TiO2催化剂的性能，为设计高效负载型Pd催化剂提供了新思路。

2. Pt/N-TiO2催化剂研究

论文标题： "Highly Effective N-TiO2 Supported Pt Catalyst for Selective Hydrogenation of Nitroarenes under Mild Conditions"

作者： Li等

发表期刊： Industrial & Engineering Chemistry Research (2015)

研究亮点： 该论文报道了一种高效的N-TiO2负载Pt催化剂，在硝基芳烃选择性加氢反应中表现出优于未掺杂Pt/TiO2催化剂的催化性能pubs.acs.org。研究表明，N掺杂不仅增强了催化剂对可见光的吸收，还改变了表面电子结构，Pt与N-TiO2表面形成了强相互作用。这种催化剂在温和条件下实现了硝基芳烃的高效选择性加氢。

该研究的价值在于：提供了一种简便有效的方法来提高Pt/TiO2催化剂在选择性加氢反应中的活性和选择性，对精细化工合成具有重要应用前景。

3. Ru/N-TiO2催化剂研究

论文标题： "Structural effects of nitrogen-doped titanium oxide supports on stabilization of ruthenium active species in carbon dioxide hydrogenation to formate"

作者： Park等

发表期刊： Applied Catalysis B: Environmental (2023)

研究亮点： 该论文探究了单原子Ru催化剂负载在N掺杂TiO2上用于CO2加氢制甲酸盐的性能。研究发现，N掺杂位点为Ru单原子催化剂提供了强结合环境，使其保持稳定的原子级分散状态researchgate.net。特别是同时含有取代型(Ns)和间隙型(Ni)掺杂位点的Ru/MN-TiO2表现出增强的催化稳定性，在第五次循环测试后仍保持42%的原始相对活性，远优于未掺杂的Ru/TiO2researchgate.net。

该研究的突破在于：揭示了不同类型氮掺杂位点对Ru单原子催化剂稳定性的影响机制，为开发高效稳定的CO2转化催化剂提供了新思路。

4. AuPd/N-TiO2催化剂研究

论文标题： "AuPd/N-TiO2上的高效甲酸脱氢：N掺杂剂的作用和TiO2晶相的影响"

发表年份： 2023年

研究亮点： 该研究通过氨基功能化钛金属有机骨架NH2-MIL-125(Ti)在空气中直接热解制备氮掺杂TiO2(N-TiO2)，并将高度分散的AuPd纳米颗粒锚定在N-TiO2上www.x-mol.com。研究发现，在60℃时，Au2Pd8/N-TiO2催化的脱氢反应总周转频率值达7725 h-1，是无氮催化剂(Au2Pd8/TiO2)的2.9倍www.x-mol.com。N的存在可以增强AuPd与载体之间的相互作用，有效阻止AuPd在载体表面的聚集，提高催化剂的催化活性和可重复使用性www.x-mol.com。

该研究的价值在于：结合实验与理论计算，为甲酸脱氢催化剂的改性提供了一种新的方法，对氢能源开发具有重要意义。

N掺杂TiO2负载金属催化剂的制备方法与效果比较

下表总结了不同类型N掺杂TiO2负载金属催化剂的制备方法与主要应用效果：

催化剂类型主要应用催化性能N掺杂效果金属-载体相互作用关键参考文献
Pd/N-TiO2硝基芳烃选择性加氢高活性和稳定性，硝基苯加氢反应中表现优于Pd/TiO2促进Pd高分散，形成亚2nm Pd纳米颗粒形成强耦合Pd-N物种，有利于硝基苯的解离吸附和苯胺产物的脱附Chen et al., 2017, ACS Catalysis
Pt/N-TiO2硝基芳烃选择性加氢，光催化降解有机污染物在硝基芳烃加氢中表现出高选择性，优于未掺杂Pt/TiO2增强催化剂对可见光吸收，改变表面电子结构Pt与N-TiO2表面形成强相互作用，需要比Pt纳米颗粒更高的还原温度Li et al., 2015, Ind. Eng. Chem. Res.
Ru/N-TiO2CO2加氢制甲酸盐，CO2甲烷化高催化稳定性，第五次循环后仍保持42%初始活性N掺杂位点为Ru单原子提供强结合环境取代型N掺杂(Ns)对Ru的结合能力强于间隙型N掺杂(Ni)和纯TiO2表面Park et al., 2023, Applied Catalysis B
AuPd/N-TiO2甲酸脱氢产氢60℃时脱氢反应总周转频率达7725 h-1，是无氮催化剂的2.9倍锐钛矿型TiO2含量高，N-TiO2载体与金属纳米粒子之间协同效应增强N的存在增强AuPd与载体间相互作用，有效阻止AuPd在载体表面聚集2023年研究报道

从上表可以看出，不同金属负载的N-TiO2催化剂在各自的应用领域均表现出优异性能。N掺杂对不同金属催化剂的影响机制虽有差异，但都体现了对金属分散度、电子态和催化性能的积极调控作用。

N掺杂TiO2负载金属催化剂的协同作用机理

N掺杂TiO2负载金属催化剂的优异性能源于多重协同效应，主要包括以下几个方面：

  1. 电子结构调控：N掺杂在TiO2禁带中引入中间能级，缩小带隙，拓展光吸收至可见光区。这使得N掺杂TiO2在可见光下也能产生光生电子-空穴对，大大提高了光能利用效率。

  2. 金属分散度提高：N掺杂位点为金属提供锚定位点，防止金属纳米颗粒团聚。例如，在Pd/N-TiO2催化剂中，N掺杂促进了Pd在TiO2表面的高分散，形成稳定的亚2nm Pd纳米颗粒，这对提高催化活性至关重要。

  3. 强金属-载体相互作用(SMSI)：

    • 取代型N掺杂(Ns)对金属的结合能力强于间隙型N掺杂(Ni)和纯TiO2表面
    • 形成M-N强耦合物种，调控金属的电子态

  4. 反应动力学优化：

    • 促进反应物(如硝基苯、CO2)的吸附活化
    • 优化产物(如苯胺、甲酸盐)的脱附过程
    • 提高催化剂的选择性和稳定性

  5. 光催化协同效应：

    • 可见光激发N-TiO2产生电子-空穴对
    • 金属作为电子捕获中心，抑制电子-空穴复合
    • 捕获的电子参与反应物的还原反应

总结与展望

N掺杂TiO2负载金属催化剂因其在可见光催化、选择性加氢、CO2转化等领域的优异性能，已成为催化研究的热点。上述推荐的论文从不同角度阐述了N掺杂对TiO2负载金属催化剂性能的影响机制，为该领域的深入研究提供了重要参考。

未来研究可进一步探索：

  1. 精确调控N掺杂类型(取代型vs间隙型)及其对不同金属催化性能的影响
  2. 开发新型N掺杂TiO2负载金属催化剂用于更广泛的反应
  3. 深入研究N掺杂与其他非金属掺杂(如C、S等)的协同效应
  4. 探索N掺杂TiO2负载金属催化剂在实际工业应用中的可行性

这些研究将有助于开发更高效、更稳定的催化材料，推动绿色化学和可持续能源的发展。

Source(83)
文件
[PDF] 可见光活性掺杂 T iO 改性研究进展
文件
[PDF] ORIGINAL RESEARCH ARTICLE
文件
[PDF] Nitrogen and Carbon Nitride-Doped TiO for Multiple Catalysis and Its Antimicrobial Activity
文件
[PDF] (19)中华人民共和国国家知识产权局
sciencedirect.com
by K Park · 2023 · Cited by 22 — A single atom Ru catalyst supported on a N-doped TiO2 was investigated for the conversion of CO2 to formate by hydrogenation.
pubs.rsc.org
by J Zhang · 2010 · Cited by 771 — This paper presents a critical review of novel achievements in the modification of N–TiO 2 photocatalytic systems aimed at enhancing TiO 2 applications.
手机知网
<em>TiO2</em> 氮<em>掺杂 金属</em>修饰 光<em>催化</em> 丙烯 苯酚 期刊全文库 学位<em>论文</em>库 会议<em>论文</em>库 年鉴全文库 学术百科 工具书 个人查重 我的账户 基础科学|工程科技I辑|工程科技II辑|医药卫生科技|信息科技|农业科技|哲学与人文科学|社会科学I辑|社会科学II辑|经济管理 问答 个人查重&gt;&gt;个人AIGC检测&gt;&gt;
X技术
本发明属于催化剂领域，尤其涉及金属掺杂纳米TiO2光催化剂及其制备方法。 背景技术： TiO2光催化技术近年来在空气治理和污水处理方面的研究越来越广泛，对于环境的可持续发展具有深远意义。但是由于
m.fanwen118.com
然而，由于锐钛矿型 TiO 2 的禁带宽度为 3.2 ev，只对紫外光有吸收能力，限制了 TiO 2 在可见光下的光催化能力。随着人们对太阳能资源有效利用的迫切需求，为了拓宽 TiO 2 的光吸收宽度，人们通常通过采取金属（Fe [11] 、Ni、Cr等）/非金属（N [12] 、C、B、S等）的掺杂方式，加强 TiO 2 的光催化降解能力，将光吸收宽度扩大至可将光区域。最近，有报道关于N [13] 、S [14] 、C [15] 、F和N [16] 共掺杂到具有（001）面的锐钛矿 TiO 2 催化剂中，均表现出良好的可见光光催化性能。虽然，关于过渡金属 Fe 掺杂到 TiO 2 催化剂中的可见光催化性能研究已经报道很多 [11,17] ，但关于 Fe 元素掺杂的具有（001）面的锐钛矿 TiO 2 催化剂的紫外/可见光催化性能还未有人研究。而且，多级 TiO 2 纳米片通常具有很高的结晶度，通过利用温和的手段在后处理时进行掺杂不太可能，另外，在反应过程中通过添加掺杂剂的前体会对晶体的成核与生长产生很大影响以至于得不到我们预想的结构和形貌 [12] 。
好发表
摘要： 半导体光催化剂因可以直接利用太阳光进行光催化且不产生二次污染,成为一种应用于环境污染治理领域较为理想的材料。其中TiO2光催化剂具有较高的光稳定性、良好的化学性质、无毒、较低的成本、高的光催化效率等特点,目前受到广泛的研究与关注。然而,TiO2快速复合的电子-空穴及较大的禁带宽度等自身缺陷,导致其量子产率不高,TiO2中的电子只能在紫外光下被激发,这些因素使得它的光催化性能受到了制约。因此,近年来通过研究不同的金属元素掺杂TiO2基光催化剂及研究不同特殊微纳结构来克服TiO2自身缺陷以改善其光催化性能并取得较大的进展。研究发现,通过将不同金属(如Ag、Fe、Cu、Ce等)以一元、二元、多元的形式掺入TiO2中,可改善TiO2的自身缺陷,并在催化剂表面产生不同作用,使其光响应范围增大,光催化性能显著提升。此外,研究者们还发现,特殊微纳结构的存在可以加快金属掺杂TiO2基光催化材料的电子转移,从而提高TiO2光生电子-空穴的分离效率,增加了其量子产率。金属掺杂后,TiO2对有机物的降解率及其产氢能力、光能转化率都得到了显著的提高,使其不仅在紫外光下具有优异的性能,而且在可见光下也能进行良好的光催化。掺杂后TiO2的抗菌效果与防雾性能也得到了显著的提升。本文一方面综述了不同金属掺杂体系(一元、二元复合以及多元复合掺杂)对TiO2结构及其光催化性能的改变,总结不同制备工艺对TiO2结构与性能的影响规律,并分析光催化性能的增强机制。另一方面概述了金属掺杂TiO2基复合材料的一些特殊微纳结构包括石墨烯包覆结构、核-壳结构以及其他结构的制备工艺,并讨论了不同微纳结构与金属掺杂在增强TiO2光催化性能上所起的作用。最后简单综述了不同金属掺杂TiO2纳米复合材料的不同应用,展望了未来研究方向及�
zhangqiaokeyan.com
mechanism of doped was analyzed.The photocatalytic activities were highest when the proportion of N-doped was n(N): n (TiO2) =4:1 and Ag-doped was n(Ag of co-doped TiO2 (molar ratio n (TiO2)∶ n (N)∶ n (Ag) = 1∶ 4∶ 0.02) was higher than single-doped.The degradation rates was∶ pure TiO2, 40％; N-doped, 75 ％; Ag-doped, 70％ and co-doped, 84％ respectively.It proved that the mechanisms of metal-doped and non-metal-doped affected together in co-doped photocatalyst
中国地质图书馆
在“ ACS电子期刊 ”中， 命中： 93 条，耗时：0.0469503 秒 在所有数据库中总计命中： 392 条 1. Experimental and Theoretical Understanding of Nitrogen -Doping-Induced Strong Metal–Support Interactions in Pd/ TiO2 Catalysts for Nitrobenzene Hydrogenation 作者： Peirong Chen ; Abhishek Khetan ; Fengkai Yang ; Vadim Migunov ; Philipp Weide ; Sascha P. Stürmer ; Penghu Guo ; Kevin Kähler ; Wei Xia ; Joachim Mayer ; Heinz Pitsch ; Ulrich Simon ; Martin Muhler 刊名：ACS Catalysis 出版年：2017 2. Ultraviolet Radiation Induced Dopant Loss in a TiO2 Photocatalyst 作者： Nicholas P. ChadwickAndreas Kafizas ; Raul Quesada-Cabrera ; Carlos Sotelo-Vazquez ; Salem M. Bawaked ; Mohamed Mokhtar ; Shaeel A. Al Thabaiti ; Abdullah Y. Obaid ; Sulaiman N. Basahel ; James R. Durrant ; Claire J. CarmaltIvan P. Parkin 刊名：ACS Catalysis 出版年：2017 3. External Water-Free Approach toward TiO2 Nanoparticles Embedded in Biomass-Derived Nitrogen - Doped Carbon 作者： Siyang Gao ; Yong Yan ; Ge Chen 刊名：ACS Sustainable Chemistry & Engineering 出版年：2016 4. Synthesis, Characterization, and Tribological Evaluation of TiO2 -Reinforced Boron and Nitrogen co- Doped Reduced Graphene Oxide Based Hybrid Nanomaterials as Efficient Antiwear Lubricant Additives 作者： Vinay Jaiswal ; Kalyani ; Sima Umrao ; Rashmi B. Rastogi ; Rajesh Kumar ; Anchal Srivastava 刊名：ACS Applied Materials & Interfaces 出版年：2016 5. Influence of Different Defects in Vertically Aligned Carbon Nanotubes on TiO
中国地质图书馆
在“ ACS电子期刊 ”中， 命中： 58 条，耗时：0.012024 秒 在所有数据库中总计命中： 478 条 1. Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/ TiO2 Catalysts for Nitrobenzene Hydrogenation 作者： Peirong Chen ; Abhishek Khetan ; Fengkai Yang ; Vadim Migunov ; Philipp Weide ; Sascha P. Stürmer ; Penghu Guo ; Kevin Kähler ; Wei Xia ; Joachim Mayer ; Heinz Pitsch ; Ulrich Simon ; Martin Muhler 刊名：ACS Catalysis 出版年：2017 2. Synthesis, Characterization, and Tribological Evaluation of TiO2 -Reinforced Boron and Nitrogen co - Doped Reduced Graphene Oxide Based Hybrid Nanomaterials as Efficient Antiwear Lubricant Additives 作者： Vinay Jaiswal ; Kalyani ; Sima Umrao ; Rashmi B. Rastogi ; Rajesh Kumar ; Anchal Srivastava 刊名：ACS Applied Materials & Interfaces 出版年：2016 3. Metal–Organic Framework-Templated Synthesis of Bifunctional N- Doped TiO2 –Carbon Nanotablets via Solid-State Thermolysis 作者： Yifan Gu ; Kuan Cheng ; Yi-nan Wu ; Ying Wang ; Catherine Morlay ; Fengting Li 刊名：ACS Sustainable Chemistry & Engineering 出版年：2016 4. Exceptional Visible-Light Activities of TiO2 - Co upled N- Doped Porous Perovskite LaFeO3 for 2,4-Dichlorophenol De co mposition and CO2 Conversion 作者： Muhammad Humayun ; Yang Qu ; Fazal Raziq ; Rui Yan ; Zhijun Li ; Xuliang Zhang ; Liqiang Jing 刊名：Environmental Science & Technology 出版年：2016 5. High H2 Evolution from Quantum Cu(II) Nanodot- Doped Two-Dimensi
pubs.acs.org
by Z Xiong · 2022 · Cited by 19 — The results showed that N-TiO2/N-GO catalysts had the highest activity compared with other catalysts due to the improvement of charge separation ...
SpringerOpen
by M Ocampo-Gaspar · 2025 — To develop better photocatalysts, pure and nitrogen-doped TiO 2 (TiO 2 :N) nanoparticles have been synthesized and widely studied.
link.springer.com
by S Du · 2022 · Cited by 112 — This review aims to provide a comprehensive update and description of the recent developments of N-doped TiO 2 materials for visible light-responsive ...
mdpi.com
by N Kovalevskiy · 2022 · Cited by 27 — This paper describes the chemical engineering aspects for the preparation of highly active and stable nanocomposite photocatalysts based on N-doped TiO2.
National Institutes of Health (.gov)
by ÓR Andrade · 2022 · Cited by 39 — Abstract. The objective of this work was to analyze the effect of carbon support on the activity and selectivity of N-doped TiO2 nanoparticles.
researchgate.net
Interstitial N-Doped TiO2 for Photocatalytic Methylene Blue Degradation under Visible Light Irradiation. MDPI. Catalysts. October 2024; 14(10): ...
nature.com
by M Narimani · 2025 · Cited by 6 — This study is focused on the synthesis and evaluation of TiO2 and N-doped Ti3O5 for the photocatalytic degradation of phenol as a noxious substance commonly ...
百度学术
展开 关键词：TiO_2 N掺杂 光催化 机理 TiO_2 N-doped photocatalysis mechanismDOI：CNKI:CDMD:2.2009.242978来源学校重庆工商大学文献可以 啦~欢迎点我试用！
好发表
摘要： 半导体光催化剂因可以直接利用太阳光进行光催化且不产生二次污染,成为一种应用于环境污染治理领域较为理想的材料。其中TiO2光催化剂具有较高的光稳定性、良好的化学性质、无毒、较低的成本、高的光催化效率等特点,目前受到广泛的研究与关注。然而,TiO2快速复合的电子-空穴及较大的禁带宽度等自身缺陷,导致其量子产率不高,TiO2中的电子只能在紫外光下被激发,这些因素使得它的光催化性能受到了制约。因此,近年来通过研究不同的金属元素掺杂TiO2基光催化剂及研究不同特殊微纳结构来克服TiO2自身缺陷以改善其光催化性能并取得较大的进展。研究发现,通过将不同金属(如Ag、Fe、Cu、Ce等)以一元、二元、多元的形式掺入TiO2中,可改善TiO2的自身缺陷,并在催化剂表面产生不同作用,使其光响应范围增大,光催化性能显著提升。此外,研究者们还发现,特殊微纳结构的存在可以加快金属掺杂TiO2基光催化材料的电子转移,从而提高TiO2光生电子-空穴的分离效率,增加了其量子产率。金属掺杂后,TiO2对有机物的降解率及其产氢能力、光能转化率都得到了显著的提高,使其不仅在紫外光下具有优异的性能,而且在可见光下也能进行良好的光催化。掺杂后TiO2的抗菌效果与防雾性能也得到了显著的提升。本文一方面综述了不同金属掺杂体系(一元、二元复合以及多元复合掺杂)对TiO2结构及其光催化性能的改变,总结不同制备工艺对TiO2结构与性能的影响规律,并分析光催化性能的增强机制。另一方面概述了金属掺杂TiO2基复合材料的一些特殊微纳结构包括石墨烯包覆结构、核-壳结构以及其他结构的制备工艺,并讨论了不同微纳结构与金属掺杂在增强TiO2光催化性能上所起的作用。最后简单综述了不同金属掺杂TiO2纳米复合材料的不同应用,展望了未来研究方向及�
zhangqiaokeyan.com
mechanism of doped was analyzed.The photocatalytic activities were highest when the proportion of N-doped was n(N): n (TiO2) =4:1 and Ag-doped was n(Ag of co-doped TiO2 (molar ratio n (TiO2)∶ n (N)∶ n (Ag) = 1∶ 4∶ 0.02) was higher than single-doped.The degradation rates was∶ pure TiO2, 40％; N-doped, 75 ％; Ag-doped, 70％ and co-doped, 84％ respectively.It proved that the mechanisms of metal-doped and non-metal-doped affected together in co-doped photocatalyst
mdpi.com
by Z Zhang · 2024 · Cited by 8 — Our work offers a facile strategy for the preparation of N-TiO 2 with Vo via the annealing treatment with urea.
link.springer.com
by X Li · 2024 · Cited by 9 — Herein, we engineered ruthenium (Ru) FTS catalysts supported on N-doped carbon overlayers on TiO2 nanoparticles. By regulating the carbonization ...
sciencedirect.com
by DH Lim · 2024 · Cited by 19 — This study offers deep insights into the practical utility of N–TiO 2 for the photocatalytic mineralization of aldehyde VOCs.
pubs.rsc.org
by P Zhang · 2024 · Cited by 63 — Photocatalytic fixation of nitrogen to ammonia with a Ce/S co-doped TiO2 catalyst: synergistic tuning of heterovalent metal states and oxygen vacancy defects†.
pubs.acs.org
This work will inspire the development and study of visible-light photocatalysts for photocatalytic hydrogen production. ACS Publications.
文件
[PDF] An Overview of Palladium-Catalyzed Nalkylation Reactions
sciencedirect.com
by Y Dong · 2025 · Cited by 6 — The Pt/N–TiO2–ST catalyst exhibits high catalytic performance with hydrogenation of FAL to FOL. Abstract. Highly efficient synthesis of valuable ...
pubs.acs.org
In the selective hydrogenation of nitroarenes, TiO2- supported catalysts have been developed in previous reports.32−34 It has been found that ...
papers.ssrn.com
The Pt/TiO2@CN-x. 10 catalyst was further loaded with Pt NPs on the support and finally synthesized. 11 successfully. In contrast, TiO2@CN-525 and Pt/TiO2@C ...
百度学术
并且根据DFT计算,分析了SiC表面氧的作用,SiC表面部分氧化后,仍保持对Pd的较高结合能,同时大幅增强了催化剂对中间体的吸附,降低了ORR关键电化学步骤的吉布斯自由能,从而提高了ORR性能。(4)通过在氨气气氛下高温煅烧TiO_2(B),制备了N掺杂TiO_2(N-TiO_2),并采用直接热解法将Pd NPs(平均粒径为2.8 nm)负载到N-TiO_2上,制得Pd/N-TiO_2催化剂。研究结果表明,随着煅烧温度的升高(700,800,900℃),N-TiO_2中Ti-O逐渐减少(55.1%减少至43.1%),而Ti-N-O、Ti-N逐渐增多(25.9%增加至31.9%,19.0%增加至25.0%),说明N部分取代了TiO_2中的O,TiO_2表面生成了具有氧还原活性的TiO_xN_y和具有导电性质的TiN,而且负载Pd NPs后,发生了由载体到Pd的电子转移,促进了Pd基催化剂氧还原活性的提高。同时,由于Pd与载体之间的强相互作用,使催化剂也具有较强的稳定性。
www.x-mol.com
通过氨基功能化钛金属有机骨架NH 2 -MIL -125(Ti)在空气中直接热解制备氮掺杂TiO 2 (N-TiO 2 )，并将高度分散的AuPd纳米颗粒锚定在N-TiO 2 上。合成的催化剂表现出优异的甲酸脱氢活性。60℃时,Au 2 Pd 8 /N-TiO 2 催化的脱氢反应总周转频率值为7725 h -1 ,是无氮催化剂(Au 2 Pd 8 /TiO 2 )的2.9倍。相同条件下。Au 2 Pd的优异性能 8 /N-TiO 2 催化剂归因于锐钛矿型TiO 2 含量高、N-TiO 2 载体与金属纳米粒子之间的协同效应、Au与Pd之间的合金化效应以及金属粒子的小尺寸。N的存在可以增强AuPd与载体之间的相互作用，有效阻止AuPd在载体表面的聚集，提高催化剂的催化活性和可重复使用性。 TiO 2晶相（锐钛矿和金红石）和N掺杂对Au 2 Pd 8 /N-TiO 2 性能的影响 通过理论计算分析了-催化的甲酸分解。结果表明，锐钛矿基和N-TiO 2 基催化剂可以降低甲酸脱氢的势垒。该工作将实验与理论计算相结合，为甲酸脱氢催化剂的改性提供了一种新的方法。
zhangqiaokeyan.com
考察了Pt促进的N掺杂TiO2(Pt/N-TiO2)催化剂对光催化降解有机污染物性能的影响及其作用本质.采用X射线衍射、透射电镜、X射线光电子能谱、紫外-可见漫反射光谱、光电化学和荧光光谱等手段对催化剂进行了表征,并考察了样品在可见光下光催化降解甲基橙(MO)的反应性能.结果表明,Pt的存在并未明显改变N-TiO2的晶相和介孔结构,却增强了催化剂对可见光吸收,但这种背景吸收不利于光激发中心(N-TiO2)对可见光的吸收,从而影响Pt/N-TiO2光催化活性;高度分散在N-TiO2表面的Pt,显著地改变了催化剂表面电子结构,从而提高了N-TiO2的光催化性能.%The influence of Pt as a promoter on the photocatalytic performance of nitrogen-doped TiO2 was described. The sample was characterized by X-ray diffraction. transmission electron microscopy, X-ray photoelectron spectroscopy, UV-Vis diffuse reflectance spectroscopy,photoelectrochemistry, and photoluminescence. The degradation of methyl orange in aqueous solution under visible light irradiation was used to evaluate the photocatalytic activity of the sample. The modification of N-TiO2 with Pt did not change the crystal structure and the mesoporous structure of TiO2. The loading of Pt enhanced the material absorption in visible light region, which is assigned to background absorption that has detrimental effect on photocatalytic activity. However, the highly dispersed Pt on the surface of N-TiO2 remarkably altered the surface structure (surface state) of N-TiO2. contributing largely to the enhanced photocatalytic activity of nitrogen-doped TiO2.
researchgate.net
The highest hydrogen production rate (2460 μmol h−1 g−1) was obtained when bimetallic 0.05 wt% PdO-0.10 wt% Pt/N–TiO2 was used. After three ...
sciencedirect.com
by F Li · 2025 · Cited by 4 — Inoue et al. studied Pt nanoparticle-decorated TiO2 and Pd-supported TiO2-x for HER, the excellent catalytic performance benefits from the role ...
mdpi.com
by D Zhao · 2024 · Cited by 40 — Noble metal ions like Pt, Pd, Au, Ag, and Ru can extend the light absorption range of TiO2 to VIS light by reducing the Eg and enhanc the hydrogen evolution ...
National Institutes of Health (.gov)
by JC Medina · 2024 · Cited by 1 — The aim was to evaluate the effect of three different metals on nitrogen-functionalized TiO2 support (Pd/N-TiO2, Pt/N-TiO2 and Au/N-TiO2) and ...
华南理工大学
... Experimental and theoretical understanding of nitrogen doping-induced strong metal-support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation.
semanticscholar.org
Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation.
谷歌
Experimental and Theoretical Understanding of Nitrogen Doping-Induced Strong Metal-Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation.
pubs.acs.org
by P Chen · 2017 · Cited by 177 — By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
researchgate.net
By doping the TiO2 support with nitrogen, strong metal-support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
中国地质图书馆
ACS电子期刊 命中： 43 条，耗时：0.0317184 秒 在所有数据库中总计命中： 1,718 条 1. Experime n tal a n d Theoretical U n dersta n di n g of Nitroge n -Dopi n g-I n duced Stro n g Metal–Support I n teractio n s i n Pd/TiO2 Catalysts for Nitrobe n ze n e Hydroge n atio n 作者： Peir o n g Che n ; Abhishek Kheta n ; Fe n gkai Ya n g ; Vadim Migu n ov ; Philipp Weide ; Sascha P. Stürmer ; Pe n ghu Guo ; Kevi n Kähler ; Wei Xia ; Joachim Mayer ; Hei n z Pitsch ; Ulrich Simo n ; Marti n Muhler 刊名：ACS Catalysis 出版年：2017 2. I n sights i n to I n terfacial Cha n ges a n d Photoelectrochemical Stability of I n xGa1‿i>xN (0001) Photoa n ode Surfaces i n Liquid E n viro n me n ts 作者： Lore n zo Caccamo ; Giulio Cocco ; Gemma Martí n ; Hao Zhou ; Sö n ke Fu n dli n g ; Alaaeldi n Gad ; Mati n Sadat Mohajera n i ; Mahmoud Abdelfatah ; So n ia Estradé ; Fra n cesca Peir ó ; Wa n ja Dzio n y ; Heiko Bremers ; A n dreas Ha n gleiter ; Leo n hard Mayrhofer ; Gerhard Lilie n kamp ; Michael Moseler ; Wi n fried Daum ; A n dreas Waag 刊名：ACS Applied Materials & I n terfaces 出版年：2016 3. 3D Visualizatio n of the Iro n Oxidatio n State i n FeO/Fe3O4 Core–Shell Na n ocubes from Electro n E n ergy Loss Tomography 作者： Pau Torruella ; Raúl Are n al ; Fra n cisco de la Peña ; Zi n eb Saghi ; Lluís Yedra ; Alberto Eljarrat ; Lluís López-Co n esa ; Marta Estrader ; Alberto López-Ortega ; Germá n Salazar-Alvarez ;
中国地质图书馆
在“ ACS电子期刊 ”中， 命中： 103 条，耗时：小于0.01 秒 在所有数据库中总计命中： 1,467 条 1. Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation 作者： Peirong Chen ; Abhishek Khetan ; Fengkai Yang ; Vadim Migunov ; Philipp Weide ; Sascha P. Stürmer ; Penghu Guo ; Kevin Kähler ; Wei Xia ; Joachim Mayer ; Hei nz Pitsch ; Ulrich Simon ; Martin Muhler 刊名：ACS Catalysis 出版年：2017 2. Molecular Design for Tailoring a Single-Source Precursor for Bismuth Ferrite 作者： Georg Bendt ; Rafael Schiwon ; Soma Salamon ; Joachim Landers ; Ulrich Hagemann ; Christian Limberg ; Hei ko Wende ; Stephan Schulz 刊名：Inorganic Chemistry 出版年：2016 3. Bay-Extended, Distorted Perylene Esters Showing Visible Luminescence after Ultraviolet Excitation: Photophysical and Electrochemical Analysis 作者： Joachim Vollbrecht ; Christian Wiebeler ; Adam Neuba ; Harald Bock ; Stefan Schumacher ; Hei nz Kitzerow 刊名：Journal of Physical Chemistry C 出版年：2016 4. Chemically Diverse Group I p21-Activated Kinase (PAK) Inhibitors Impart Acute Cardiovascular Toxicity with a Narrow Therapeutic Window 作者： Joachim Rudolph ; Lesley J. Murray ; Chudi O. Ndubaku ; Thomas O’Brien ; Elizabeth Blackwood ; Weiru Wang ; Ignacio Aliagas ; Lewis Gazzard ; James J. Crawford ; Joy Drobnick ; Wendy Lee ; Xianrui Zhao ; Klaus P. Hoeflich ; David A. Favor ; Ping Dong ;
pubs.acs.org
by P Chen · 2017 · Cited by 177 — By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
sciencedirect.com
by Y Shao · 2025 · Cited by 4 — Experimental and theoretical understanding of nitrogen-doping-induced strong metal–support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation ...
researchgate.net
By doping the TiO2 support with nitrogen, strong metal-support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
pubs.acs.org
by P Chen · 2017 · Cited by 177 — By doping the TiO2 support with nitrogen, strong metal–support interactions (SMSI) in Pd/TiO2 catalysts can be tailored to obtain high-performance supported ...
sciencedirect.com
by Y Shao · 2025 · Cited by 4 — Experimental and theoretical understanding of nitrogen-doping-induced strong metal–support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation ...
中国地质图书馆
ACS电子期刊 命中： 43 条，耗时：0.0317184 秒 在所有数据库中总计命中： 1,718 条 1. Experime n tal a n d Theoretical U n dersta n di n g of Nitroge n -Dopi n g-I n duced Stro n g Metal–Support I n teractio n s i n Pd/TiO2 Catalysts for Nitrobe n ze n e Hydroge n atio n 作者： Peir o n g Che n ; Abhishek Kheta n ; Fe n gkai Ya n g ; Vadim Migu n ov ; Philipp Weide ; Sascha P. Stürmer ; Pe n ghu Guo ; Kevi n Kähler ; Wei Xia ; Joachim Mayer ; Hei n z Pitsch ; Ulrich Simo n ; Marti n Muhler 刊名：ACS Catalysis 出版年：2017 2. I n sights i n to I n terfacial Cha n ges a n d Photoelectrochemical Stability of I n xGa1‿i>xN (0001) Photoa n ode Surfaces i n Liquid E n viro n me n ts 作者： Lore n zo Caccamo ; Giulio Cocco ; Gemma Martí n ; Hao Zhou ; Sö n ke Fu n dli n g ; Alaaeldi n Gad ; Mati n Sadat Mohajera n i ; Mahmoud Abdelfatah ; So n ia Estradé ; Fra n cesca Peir ó ; Wa n ja Dzio n y ; Heiko Bremers ; A n dreas Ha n gleiter ; Leo n hard Mayrhofer ; Gerhard Lilie n kamp ; Michael Moseler ; Wi n fried Daum ; A n dreas Waag 刊名：ACS Applied Materials & I n terfaces 出版年：2016 3. 3D Visualizatio n of the Iro n Oxidatio n State i n FeO/Fe3O4 Core–Shell Na n ocubes from Electro n E n ergy Loss Tomography 作者： Pau Torruella ; Raúl Are n al ; Fra n cisco de la Peña ; Zi n eb Saghi ; Lluís Yedra ; Alberto Eljarrat ; Lluís López-Co n esa ; Marta Estrader ; Alberto López-Ortega ; Germá n Salazar-Alvarez ;
中国地质图书馆
在“ ACS电子期刊 ”中， 命中： 103 条，耗时：小于0.01 秒 在所有数据库中总计命中： 1,467 条 1. Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation 作者： Peirong Chen ; Abhishek Khetan ; Fengkai Yang ; Vadim Migunov ; Philipp Weide ; Sascha P. Stürmer ; Penghu Guo ; Kevin Kähler ; Wei Xia ; Joachim Mayer ; Hei nz Pitsch ; Ulrich Simon ; Martin Muhler 刊名：ACS Catalysis 出版年：2017 2. Molecular Design for Tailoring a Single-Source Precursor for Bismuth Ferrite 作者： Georg Bendt ; Rafael Schiwon ; Soma Salamon ; Joachim Landers ; Ulrich Hagemann ; Christian Limberg ; Hei ko Wende ; Stephan Schulz 刊名：Inorganic Chemistry 出版年：2016 3. Bay-Extended, Distorted Perylene Esters Showing Visible Luminescence after Ultraviolet Excitation: Photophysical and Electrochemical Analysis 作者： Joachim Vollbrecht ; Christian Wiebeler ; Adam Neuba ; Harald Bock ; Stefan Schumacher ; Hei nz Kitzerow 刊名：Journal of Physical Chemistry C 出版年：2016 4. Chemically Diverse Group I p21-Activated Kinase (PAK) Inhibitors Impart Acute Cardiovascular Toxicity with a Narrow Therapeutic Window 作者： Joachim Rudolph ; Lesley J. Murray ; Chudi O. Ndubaku ; Thomas O’Brien ; Elizabeth Blackwood ; Weiru Wang ; Ignacio Aliagas ; Lewis Gazzard ; James J. Crawford ; Joy Drobnick ; Wendy Lee ; Xianrui Zhao ; Klaus P. Hoeflich ; David A. Favor ; Ping Dong ;
National Institutes of Health (.gov)
by H Zou · 2021 · Cited by 75 — ... theoretical understanding of nitrogen-doping-induced strong metal–support interactions in Pd/TiO2 catalysts for nitrobenzene hydrogenation.
researchgate.net
This review seeks to provide a consolidated view of the current understanding of SMSI in TiO2‐supported metal catalysts. It highlights the ...
pubs.acs.org
Herein, an efficient N-TiO2 supported Pt catalyst was synthesized, which exhibits better catalytic performance than an undoped Pt/TiO2 catalyst in the ...
researchgate.net
Tuning of catalytic sites in Pt/TiO2 catalysts for the chemoselective hydrogenation of 3-nitrostyrene. Article. Full-text available. Oct 2019.
acs.figshare.com
Herein, an efficient N-TiO2 supported Pt catalyst was synthesized, which exhibits better catalytic performance than an undoped Pt/TiO2 catalyst ...
X-MOL
图4. Pt/Ti O 2 -TCO催化性能评价: (a-d) Pt/TiO 2 -TCO (T: 200-600 °C)催化剂对4-NS的选择性加氢，(e) 0.05 wt% Pt/TiO 2 -SAC催化剂上4-NS的加氢(反应条件：4-NS, 0.5 mmol; 催化剂, 90 mg; EtOH, 5 mL; P H2 , 0.5 MPa; T, 60°C)，(f) 硝基苯和苯乙烯混合物加氢，(g) 4-VA在60°C下6.0 h内加氢反应趋势, (h, i) Pt/TiO 2 -600CO在半转化和全转化条件下4-NS选择性加氢的循环稳定性(反应条件：4-NS或4-VA, 0.5 mmol; 催化剂, 10 mg; EtOH, 5 mL; P H2 , 0.5 MPa; T, 60°C, t, 50或120 min)。
掌桥科研
The hydrogenation of crotonaldehyde in the presence of supported platinum nanoparticles was used to determine how the interaction between the metal particles and their support can control catalytic performance.Using gas-phase catalytic reaction studies and in situ sum-frequency generation vibrational spectroscopy (SFG) to study Pt/TiO2 and Pt/SiO2 catalysts, a unique reaction pathway was identified for Pt/TiO2, which selectively produces alcohol products.
AmazonAWS
Highly effective N-TiO2 supported Pt catalyst for selective hydrogenation of nitroarenes under mild conditions. Jing Lia, XinweiDu a, Yujing ...
sciencedirect.com
by Y Dong · 2025 · Cited by 6 — The Pt/N–TiO2–ST catalyst exhibits high catalytic performance with hydrogenation of FAL to FOL. Abstract. Highly efficient synthesis of valuable ...
mdpi.com
In this study, we synthesized a series of catalysts comprising TiO2-supported Pt nanoparticles with varying particle sizes, which were systematically evaluated ...
nature.com
by W Tolek · 2021 · Cited by 53 — The presence of high anatase crystallographic composition on TiO2 support was favorable for enhancing hydrogenation activity, while the strong ...
docs.nrel.gov
Such an approach, involving TiO2-overcoated Pd and Pt catalysts, has shown promise for improving the activity and selectivity for aromatic.
文件
[PDF] Light-assisted carbon dioxide reduction in an automated photoreactor system coupled to carbonylation chemistry
文件
[PDF] (19)中华人民共和国国家知识产权局
文件
[PDF] Advances in the studies of the supported ruthenium catalysts for $\mathbf { C O } _ { 2 }$ methanation
researchgate.net
A single atom Ru catalyst supported on a N-doped TiO2 was investigated for the conversion of CO2 to formate by hydrogenation. N-dopant sites ...
sciencedirect.com
by KR Lee · 2025 · Cited by 2 — We developed a rational strategy to enhance the catalytic performance of Ru catalysts supported on mesoporous N-doped TiO 2 for CO 2 hydrogenation.
ccspublishing.org.cn
In summary, the Ru-doped TiO2 photocatalysts with tunable oxygen vacancies have been successfully synthesized by using ascorbic acid as a reducing agent. In a ...
掌桥科研
机译： 一锅超临界合成制备的N掺杂TiO2基光催化剂光催化还原CO2 获取原文 获取原文并翻译 | 示例 摘要 The objective of this work was to analyze the effect of carbon support on the activity and selectivity of N-doped TiO2 nanoparticles. Thus, N-doped TiO2 and two types of composites, N-doped TiO2/CNT and N-doped TiO2/rGO, were prepared by a new environmentally friendly one-pot method. CNT and rGO were used as supports, triethylamine and urea as N doping agents, and titanium (IV) tetraisopropoxide and ethanol as Ti precursor and hydrolysis agent, respectively. The as-prepared photocatalysts exhibited enhanced photocatalytic performance compared to TiO2 P25 commercial catalyst during the photoreduction of CO2 with water vapor. It was imputed to the synergistic effect of N doping (reduction of semiconductor band gap energy) and carbon support (enlarging e(-)-h(+) recombination time). The activity and selectivity of catalysts varied depending on the investigated material. Thus, whereas N-doped TiO2 nanoparticles led to a gaseous mixture, where CH4 formed the majority compared to CO, N-doped TiO2/CNT and N-doped TiO2/rGO composites almost exclusively generated CO. Regarding the activity of the catalysts, the highest production rates of CO (8 mu mol/gTiO(2)/h) and CH4 (4 mu mol/gTiO(2)/h) were achieved with composite N-1/TiO2/rGO and N-1/TiO2 nanoparticles, respectively, where superscript represents the ratio mg N/g TiO2. These rates are four times and almost forty times higher than the CO and CH4 production rates observed wi
百度
In this work, we reported Ru nanoparticles (NPs) (<5 nm) supported on titanium dioxide (TiO2) using the facile and fast molten-salt method and employed Moreover, the catalytic applications of Ru/TiO2 were explored for the reductive amination of nitrobenzene and furfural with excellent conversion (>99%) catalyst compared to as-synthesized Cu/TiO2, and Ni/TiO2.
jmonline.org
N-doped and oxygen-deficient titanium dioxide was synthesized by heating TiO2 in NH3 atmosphere,followed by the post-calcination in H2 for different time.The TiO2 post-heated in H2 atmosphere for 1 h exhibited the high photocatalytic activity.After photocatalytic oxidation for 5 h,the conversion rate and mineralization than that of the sums on N-doped TiO2 and oxygen-deficient TiO2.The enhanced photoactivity of the co-doped catalysts is related to a synergistic effect
百度学术
展开 TiO2 modified Al2O3 binary oxide was prepared by a wet-impregnation method and used as the support for ruthenium catalyst. The catalytic performance of Ru/...CO2 methanation is an important probe reaction to understand CO2 interactions with catalytic surfaces. The importance of this reaction is further increased by its association with CO2 utilization. This study reports the mechanistic aspec...
link.springer.com
To address the limitations of carbon materials, such as high cost, low mechanical strength, and hydrophobic nature, Park et al*.* [57] developed a Ru SAC catalyst supported on N-doped TiO2. TiO2 was chosen for its stability, non-toxicity, and affordability, making it a practical alternative. Additionally, TiO2 is commonly used in photocatalysis and can be effectively doped with nitrogen, which can either be substitutional (Ns) or interstitial (Ni) introducing N-doped sites that facilitate the coupling of metallic species like Ru, ensuring effective dispersion and distribution of the metal catalyst within the support. Two methods were employed to synthesize the catalysts with melamine as the nitrogen source and different support precursors. The use of titanium isopropoxide (MN-TiO2) promoted the formation of both Ns and Ni sites (Fig. 11a), while titanium dioxide (N-TiO2) favored Ni sites (Fig. 11b). Various calcination temperatures were tested, with 773 K being selected based on XRD and XPS analyses. These analyses showed significant TiO2 network formation and effective N-doping due to thermal decomposition at this temperature. Additional characterization techniques confirmed the successful incorporation of Ru into the structure, its oxidation state as Ru+3, and the absence of Ru NPs, indicating a high level of atomic dispersion. In situ CO Diffuse Reflectance Infrared Fourier Transform (DRIFT) adsorption studies revealed the absence of characteristic CO bands at 1960 cm−1 as
www.x-mol.com
Here, an N-doped carbon supported Ru catalyst with an interior cavity was synthesized by etching a MOF-derived core–shell precursor, in which metal Ru This catalyst shows 98.7% conversion and >99% selectivity towards p -chloroaniline in the hydrogenation of p -chloronitrobenzene, which is better than the corresponding supported catalyst.
掌桥科研
supported on TiO2 compared to CeO2, YSZ or Al2O3. from 2.2 (for Ru/Al2O3) to 4.2 nm (for Ru/TiO2). , is a promising catalyst for the CO2 methanation reaction.
sciencedirect.com
by Y Shao · 2025 · Cited by 4 — This study shows that nitrogen (N) doping of TiO2 could achieve this, and the bimetallic CuGa supported on N doped TiO2 (CuGa/TiO2-N0.5) attained the improved ...
pubs.acs.org
by X Wang · 2022 · Cited by 18 — The present work provides a facile and feasible strategy to promote both activity and selectivity of supported catalysts in CO 2 hydrogenation.
link.springer.com
by X Li · 2024 · Cited by 9 — Herein, we engineered ruthenium (Ru) FTS catalysts supported on N-doped carbon overlayers on TiO2 nanoparticles. By regulating the carbonization ...
researchgate.net
Recently, a Ru(III) catalyst on a N-doped carbon support achieved a turn-over frequency (TOF) as high as 2238 h − 1 ; it also showed deactivation ...
Wiley
by CB Hiragond · 2024 · Cited by 38 — Ru doping followed by Ag nanoparticles (NPs) cocatalyst deposition on P25 (TiO2) enhances visible light absorption and charge separation, ...